Circularly Polarized Luminescence of Boronic Acid-Derived Salicylidenehydrazone Complexes Containing Chiral Boron as Stereogenic Unit
Racemic mixtures of boronic acid-derived salicylidenehydrazone (BASHY) complexes were enantiomerically resolved. The chiroptical properties of the stereoisomers, containing an asymmetric boron as the only stereogenic unit, are translated into mirror-imaged electronic circular dichroism spectra and circularly polarized luminescence (CPL, dissymmetry factors of 3–5 × 10–4) is observed. The spectral position of the CPL emission is determined by the push–pull character of the dye. These features expand the functional scope of the brightly emitting BASHY dye platform.
https://pubs.acs.org.ccindex.cn/doi/10.1021/acs.joc.8b01844
