{"id":13773,"date":"2019-02-18T23:28:21","date_gmt":"2019-02-18T15:28:21","guid":{"rendered":"https:\/\/www.bihec.com\/olisclarity\/?p=13773"},"modified":"2019-02-18T23:29:27","modified_gmt":"2019-02-18T15:29:27","slug":"%e5%90%ab%e6%9c%89%e6%89%8b%e6%80%a7%e7%a1%bc%e7%ab%8b%e4%bd%93%e5%8d%95%e5%85%83%e7%9a%84%e7%a1%bc%e9%85%b8%e8%a1%8d%e7%94%9f%e7%9a%84%e4%ba%9a%e6%b0%b4%e6%9d%a8%e5%9f%ba%e8%85%99%e9%85%8d%e5%90%88","status":"publish","type":"post","link":"https:\/\/www.bihec.com\/olisclarity\/%e5%90%ab%e6%9c%89%e6%89%8b%e6%80%a7%e7%a1%bc%e7%ab%8b%e4%bd%93%e5%8d%95%e5%85%83%e7%9a%84%e7%a1%bc%e9%85%b8%e8%a1%8d%e7%94%9f%e7%9a%84%e4%ba%9a%e6%b0%b4%e6%9d%a8%e5%9f%ba%e8%85%99%e9%85%8d%e5%90%88\/","title":{"rendered":"DSM 172\u7528\u4e8e\u7814\u7a76\u542b\u6709\u624b\u6027\u787c\u7acb\u4f53\u5355\u5143\u7684\u787c\u9178\u884d\u751f\u7684\u4e9a\u6c34\u6768\u57fa\u8159\u914d\u5408\u7269\u7684CPL\u5706\u504f\u632f\u53d1\u5149"},"content":{"rendered":"<p>Circularly Polarized Luminescence of Boronic Acid-Derived Salicylidenehydrazone Complexes Containing Chiral Boron as Stereogenic Unit<\/p>\n<p><img decoding=\"async\" loading=\"lazy\" class=\"alignnone size-full wp-image-13774\" src=\"https:\/\/www.bihec.com\/olisclarity\/wp-content\/uploads\/sites\/7\/2019\/02\/jo-2018-01844j_0005.gif\" alt=\"\" width=\"500\" height=\"250\" \/><\/p>\n<p>&nbsp;<\/p>\n<p>Racemic mixtures of boronic acid-derived salicylidenehydrazone (BASHY) complexes were enantiomerically resolved. The chiroptical properties of the stereoisomers, containing an asymmetric boron as the only stereogenic unit, are translated into mirror-imaged electronic circular dichroism spectra and circularly polarized luminescence (<a href=\"https:\/\/www.bihec.com\/olisclarity\/tag\/cpl\/\" title=\"View all posts in CPL\" target=\"_blank\">CPL<\/a>, dissymmetry factors of 3\u20135 \u00d7 10\u20134) is observed. The spectral position of the CPL emission is determined by the push\u2013pull character of the dye. These features expand the functional scope of the brightly emitting BASHY dye platform.<\/p>\n<p>https:\/\/pubs.acs.org.ccindex.cn\/doi\/10.1021\/acs.joc.8b01844<\/p>\n<div id=\"doi\"><strong>DOI:\u00a0<\/strong>10.1021\/acs.joc.8b01844<\/div>\n<div><\/div>\n<div><a href=\"https:\/\/www.bihec.com\/olisclarity\/dsm-172-cpl%e5%9c%86%e5%81%8f%e6%8c%af%e8%8d%a7%e5%85%89%e5%85%89%e8%b0%b1%e4%bb%aa\/\"><img decoding=\"async\" loading=\"lazy\" class=\"alignnone size-full wp-image-50\" src=\"https:\/\/www.bihec.com\/olisclarity\/wp-content\/uploads\/sites\/7\/2018\/07\/DSM-172-2.jpg\" alt=\"\" width=\"4256\" height=\"2832\" srcset=\"https:\/\/www.bihec.com\/olisclarity\/wp-content\/uploads\/sites\/7\/2018\/07\/DSM-172-2.jpg 4256w, https:\/\/www.bihec.com\/olisclarity\/wp-content\/uploads\/sites\/7\/2018\/07\/DSM-172-2-300x200.jpg 300w, https:\/\/www.bihec.com\/olisclarity\/wp-content\/uploads\/sites\/7\/2018\/07\/DSM-172-2-768x511.jpg 768w, https:\/\/www.bihec.com\/olisclarity\/wp-content\/uploads\/sites\/7\/2018\/07\/DSM-172-2-1024x681.jpg 1024w, https:\/\/www.bihec.com\/olisclarity\/wp-content\/uploads\/sites\/7\/2018\/07\/DSM-172-2-272x182.jpg 272w\" sizes=\"(max-width: 4256px) 100vw, 4256px\" \/><\/a><\/div>\n<br><div class=\"tagcloud\"><\/div>","protected":false},"excerpt":{"rendered":"<p>Circularly Polarized Luminescence of Boronic Acid-Derived Salicylidenehydrazone Complexes  <\/p>\n","protected":false},"author":1,"featured_media":13774,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_vp_format_video_url":"","_vp_image_focal_point":[]},"categories":[1],"tags":[],"_links":{"self":[{"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/posts\/13773"}],"collection":[{"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/comments?post=13773"}],"version-history":[{"count":0,"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/posts\/13773\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/media\/13774"}],"wp:attachment":[{"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/media?parent=13773"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/categories?post=13773"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.bihec.com\/olisclarity\/wp-json\/wp\/v2\/tags?post=13773"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}